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Water Science & Technology Vol 66 No 6 pp 1270–1276 © IWA Publishing 2012 doi:10.2166/wst.2012.290

Consideration of emerging pollutants in groundwater-based reuse concepts

A. Tiehm, N. Schmidt, P. Lipp, C. Zawadsky, A. Marei, N. Seder, M. Ghanem, S. Paris, M. Zemann and L. Wolf

Water Technology Center (TZW), Karlsruher Str. 84, 76139 Karlsruhe, Germany E-mail: andreas.tiehm@tzw.de
Department of Earth and Environmental Sciences, P.O. Box 20002, Al-Quds University of Jerusalem, Palestine
Jordan Valley Authority, P.O. Box 2412, 11183 Amman, Jordan
Palestinian Hydrology Group, P.O.Box 323, Ramallah, West Bank/Palestine
Huber SE, 92335 Berching, Germany
Department of Applied Geology (AGK), Karlsruhe Institute of Technology (KIT), Kaiserstraße 12, 76128 Karlsruhe, Germany
CSIRO, Queensland Biosciences Precinct, 306 Carmody Rd St Lucia Queensland, Australia 4067


ABSTRACT

Elimination of pathogens and emerging pollutants represents a key factor in integrated water resources management in arid regions. Within the SMART Jordan Valley project it is the objective of this study to assess the occurrence and examine the elimination of selected emerging pollutants and pathogens in waste water treatment and aquifer recharge. In batch and soil column studies non-chlorinated organophosphorous compounds (tri-n-butylphosphate, triphenylphosphate) and endocrine disruptors (e.g. 17-ß-estradiol, bisphenol A) proved to be biodegradable, while the X-ray contrast agents iomeprol and iopromide were eliminated in the soil columns only, and the chlorinated trialkylphosphates showed persistency. Treating waste water in a membrane bioreactor (MBR) in combination with powdered activated carbon (PAC) resulted in considerable removal rates also for the more persistent compounds such as the antiepileptic carbamazepine. Viruses were shown to be present in most of the Jordan Valley surface water samples. MBR treatment resulted in a decrease of MS2 bacteriophages used as model viruses.

Keywords: biodegradation; endocrine disruptors; membrane bioreactor; pharmaceuticals; trialkylphosphates; viruses


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