
Water Science & Technology Vol 43 No 1 pp 181190 © IWA Publishing 2000
Application of COD fractionation by a new combined technique: comparison of
various wastewaters and sources of variability
M Spérandio*, V Urbain**, P Ginestet***, MJ Audic**** and E Paul*****
*
LIPE, dépt GPI, Complexe scientifique de Rangueil, INSA, Toulouse,
31077, France
**
CIRSEE-Suez-Lyonnaise-des-Eaux, 38 Rue du Président Wilson, Le Pecq,
78230, France
***
CIRSEE-Suez-Lyonnaise-des-Eaux, 38 Rue du Président Wilson, Le Pecq,
78230, France
****
CIRSEE-Suez-Lyonnaise-des-Eaux, 38 Rue du Président Wilson, Le Pecq,
78230, France
*****
LIPE, dépt GPI, Complexe scientifique de Rangueil, INSA, Toulouse,
31077, France
ABSTRACT
A new respirometric method for COD fractionation was applied to various
wastewaters collected on French treatment plants. Great variations were
observed especially in the readily biodegradable fraction (RBCOD) ranging
from 1 to 16% of total COD. Variability of the results among the origin
can be explained by the reactions occurring in the sewers. In one of the
towns studied, the wastewater samples collected directly in the sewer
show COD characteristics very different from the sewage which reaches
the treatment plant. By analysing the same wastewater after aerobic and
anaerobic storage, it was proved that RBCOD respectively decreased or
increased significantly. Seasonal fluctuations were also quantified,
showing that RBCOD fraction decreased from 75 mg/L to 15 mg/L
during the summer whereas the variation of soluble fraction was less
important.
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