
Water Science & Technology Vol 41 No 10-11 pp 143148 © IWA Publishing 2000
The removal of acrylonitrile from aqueous solution by Fenton's
reagent and membrane filtration
CY Chang*, SH Chen**, JS Chang*** and CC Wang****
*
Department of Environmental Engineering and Health,
Chia-Nan College of Pharmacy and Science, Tainan, Taiwan
**
Department of Environmental Engineering and Health,
Chia-Nan College of Pharmacy and Science, Tainan, Taiwan
***
Department of Environmental Engineering and Health,
Chia-Nan College of Pharmacy and Science, Tainan, Taiwan
****
Department of Environmental Engineering and Health,
Chia-Nan College of Pharmacy and Science, Tainan, Taiwan
ABSTRACT
The removal of acrylonitrile by Fenton-precipitation and
Fenton-microfiltration was investigated in this study. As for
Fenton-precipitation, in the range of pH 2 to pH 4, TOC removal efficiency
decreased with the increase in pH during the Fenton-precipitation of
acrylonitrile. Fenton-microfiltration had a significant improvement on TOC
removal at pH 3 and 4 as compared with Fenton-precipitation. The highest
removal efficiency of 95% was obtained at pH 3 and the solution pH value had
a significant effect on the total permeate quantity and the rate of
accumulation. Experimental results led to the conclusion that the oxidation
caused by Fenton's reagent was predominant at pH 2. On the contrary,
coagulation was most significant at pH 3 and 4. The results indicated the
superiority of the Fenton-microfiltration process as compared with
Fenton-precipitation process for the removal of acrylonitrile from water.
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