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Water Practice & Technology © IWA Publishing 2007 |
doi10.2166/wpt.2007.047
Investigation and integrative modelling of xenobiotics discharged from urban drainage systems
F. Reinstorf1, M. Möder2, K. Osenbrück3, K. Schirmer4, G. Strauch1, R. Wennrich2,M. Schirmer1
1Dept. of Hydrogeology, UFZ Centre for Environmental Research Leipzig-Halle in the Helmholtz Association
2Dept. of Analytics , UFZ Centre for Environmental Research Leipzig-Halle in the Helmholtz Association
3Dept of Cell Toxicology, Permoserstra â e 15, 04318 Leipzig, Germany
4Dept. of Isotope Hydrology, Theodor-Lieser-Str. 4, 06120 Halle, Germany
ABSTRACT
The urban aquatic environment is increasingly polluted by low concentrated but potentially harmful
compounds such as pharmaceuticals and endocrine disruptors - so-called xenobiotics. These
substances are mainly carried by waste water. Up to now information with regard to their impact on
the urban ecosystem and human health exist for only few of them. Within an interdisciplinary
project on risk assessment of water pollution, we work on the identification of the fluxes of these
substances.
In a first step, we used a runoff formation model representing the city of Halle (Germany) and the
Saale river. The Saale river acts as surface water system collecting slope inputs along the city
traverse and sewer outflows. We investigated the anthropogenic effect on the urban water system
using indicators such as hydrological parameters, selected complex organic substances, isotopic
signatures and dissolved substances (sulphate, nitrate).
A first balance modelling showed that main ions are not very sensitive concerning the diffuse urban
input into the river. However, the concentration pattern of fragrances (tonalid, galaxolid), rare earth
elements (gadolinium) and endocrine disrupters (t-nonylphenol) point to a different pollution along
the city traverse: downstream of the sewage plant a higher load was observed in comparison to the
upstream passage. Various substance concentrations in groundwater along the city traverse showed
increasing trends.
Keywords: urban groundwater, urban surface water, xenobiotics, endocrine disruptors, pharmaceuticals,
FRAGRANCES, RARE EARTH ELEMENTS, URBAN WATER BALANCE MODELLING
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