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Journal of Water Supply: Research and Technology—AQUA Vol 58 No 6 pp 386–394 © IWA Publishing 2009 doi:10.2166/aqua.2009.114

Taste and odour problems generated in distribution systems: a case study on the formation of 2,4,6-trichloroanisole

Andreas Peter and Urs von Gunten

Eawag, Swiss Federal Institute of Aquatic Science and Technology, Ueberlandstrasse 133, CH-8600, Duebendorf, Switzerland Tel.:+41-44-8235270 Fax:+41-44-8235210 E-mail: vongunten@eawag.ch
Institute of Biogeochemistry and Pollutant Dynamics, ETH Zürich, CH-8092, Zürich, Switzerland


ABSTRACT

A taste and odour (T&O) episode in a Swiss town, where consumers complained about a musty odour in their drinking water, was investigated. The application of a combined organoleptic and instrumental method for T&O analysis allowed the identification of 2,4,6-trichloroanisole (TCA), with an odour threshold of 30 pg l-1, in the drinking water in concentrations of up to 24 ng l-1. The absence of this compound in the raw water and after treatment showed that it was formed in the distribution system. Experiments conducted in the laboratory showed that trichlorophenol as a potential precursor or chlorine as residual disinfectant played a key role in the formation of TCA, which was only formed in the presence of biofilms. Based on these results, appropriate counter-measures, such as water distribution without residual chlorine and maintenance of household particle filters, are suggested to mitigate this T&O problem.

Keywords: biofilms; chlorination; drinking water; taste and odour; trichloroanisole


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